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Depends on age and type of car. There are a ton of little things it could be, from oxygen sensors to EGR valves, to all kinds of little valve gadgets.
Check fluids first. If they are low, that's the problem. Refill, then test. If it begins overheating again soon, check water level again. If there is a leak, check water pump, hoses and the radiator itself. Park it one night over a piece of cardboard, you'll find where it's dripping.
Check to make sure nothing is stuck in front of the radiator, or that the radiator fins are clean. Air has to flow through them.
If fluids are fine, it could still be the water pump, a loose water pump or fan belt, a malfunctioning cooling fan (the one by the radiator) or even a faulty radiator cap that fails to keep proper pressure. These are a little easier to check than it sounds. Run your car until the temp gauge reaches what would be the normal temperature, then see if the fan comes on. Watch the belts to see if they flap around. If it's an electric fan, there could be a problem with the gadgets controlling it.
Look for other problems or patterns. If the car only overheats in traffic, for instance, or only when climbing. Notice whether the AC has a problem when the car overheats. There is a valve that regulates the AC that can malfunction and make the whole car think it is cooler than it is.
There are three basic things that can be happening, to sum it up. Either there is a malfunction with the radiator or water pump, so that it's leaking fluid or pressure. There is a malfunction with a sensor which tells the car to start cooling the water. This could be the thermostat or any number of sensors. By a Haynes manual, or take it to a shop. The third problem is that the exhaust and emmission valves could be malfunctioning, so that the exhaust gases are not leaving the engine properly, and thus heating the engine beyond what it can cool. For those, you either need a manual and some patients, or just a mechanic. They can run a scan on your engine and find a lot of that with little effort (but lots of money), but it's not nearly as much fun as busting your knuckles on rusty manifold while teaching your neighbors' kids a new vocabulary.
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