release small amounts of radioactive material from stacks, with which all of them are equipped. Typically the material released are radioactive gases Kr-85, small amounts of the nobel gases Xe-133, Xe-135, and, to a lesser extent, the sometimes volatile halogen isotopes I-131 and I-129. Most other fission products are not volatile, and thus are not released. In an extreme failure, such as at Chernobyl, Cesium isotopes can be released, but as all Cesium compounds are extremely soluble in water, they typically are contained in cooling or moderating water and not volatilized. Cesium does not go up the stacks.
These gases, all of which are fission products, are typically released from fuel rods that have developed cracks over the years. (An individual fuel rod can remain in a reactor for up to five years, depending on the particular reactor's fuel loading characteristics.) Of course not all fuel rods crack, but some do and the stacks represent yet another of a series of fail safe devices.
It is interesting to note that the radioactivity release from nuclear powerplants is highly regulated, while the radioactivity release from coal fired plants are not regulated at all. It actually happens that coal fired plants typically release more radioactivity than do nuclear plants, in fact on a much grander scale.
http://www.ornl.gov/info/ornlreview/rev26-34/text/colmain.htmlIt is interesting to note in the above link that the amount of released by some coal plants actually contains more energy as Uranium than the coal burned to make the Uranium containing ash.