with strong infrared absorbances.
Many compounds have much stronger absorbances than carbon dioxide and have large All of the old CFC's have such absorbances, as does the persistent, nearly indestructible compound carbon tetrafluoride, a side product of the aluminum industry (It is also a side product of the chip industry.)
Some discussion of these gases can be found in the links below. Apparently the reductions in some of the gases that are claimed to have been reduced are "voluntary." According to the link that follows, aluminum companies have reduced their output of environmentally persistent perfluorinated carbon compounds by 3,691,507 metric tons or 85%. This means that they are only emitting 650,000 metric tons of this stuff today. (I was recently informed by a Greenpeace twit that this happy state of affairs, the fact that emissions have been reduced, means that aluminum manufacture is now free of environmental impact - at least if it is used in the production of solar cells.)
http://www.eia.doe.gov/oiaf/1605/vr99data/chapter6.html Another very, very, very persistent greenhouse chemical, is sulfur hexafluoride, which replaced polychlorinated biphenyls (PCB's) in many electrical systems, notably transformers, when PCBs were found to have unacceptable toxicity.
Compounds that have only partially fluorinated, as opposed to perfluorinated (completely fluorinated), are somewhat less persistent if they can be oxidized. Under these conditions, they often decompose to give fluorophosgene, and ultimately HF, hydrofluoric acid.
The GWP, or global warming potential, of a gas is a function of the strength of it's absorbance and it's atmospheric lifetime. Arbitrarily, the GWP of carbon dioxide is 1, and all other gases are compared to carbon dioxide. Typically GWP's are given with a number of years.
If you look in the following link, it will be clear what this means:
http://yosemite.epa.gov/OAR/globalwarming.nsf/UniqueKeyLookup/SHSU5BUM9T/$File/ghg_gwp.pdf
(Scroll down to Table 2.)
You can see that the atmospheric lifetime of carbon tetrafluoride is about 50,000 years. Viewed in terms of its global warming forcing potential, after 500 years, 1 metric ton of CF4 is equivalent to the release of 10,000 metric tons of carbon dioxide. Put another way, 500 years from now, the 650,000 metric tons of CF4
stillbeing released by the aluminum industry will be equivalent to the release of 6 billion tons of carbon dioxide today. Moreover, there is no way to remove this potential from the atmosphere. In theory, one could remove CO2 from the atmosphere through biological or direct chemical means. This is not possible with CF4. So much for the lunacy of claiming that aluminum is environmentally benign.
The situation with SF6 is even worse.