"Recently, the production of hydrogen has received much attention, because of its potential application as a clean source of energy. Water splitting by a photocatalytic process using oxide semiconductors can be considered to be successful, in regard to it being aneconomic and clean technology; as a result, it can resolve the problems of energy consumption and environmentaldegradation, at least partially. Efficient conversion of solar energy has been a challenging problem, and numerous studies have been undertaken in this direction. Biomass conversion, photocatalytic cells, and photocatalytic water splitting are the best-known examples. It has been reported that some metal oxides, such as TiO2, SrTiO2, ZrO2, BaTi4O9,and CeO2,1-10 possess reasonable activities for water splitting into H2 and O2 in the stoichiometric ratio under ultraviolet (UV) and visible-light irradiation. TiO2 has been widely used in photocatalysis, because of its favorable band-gap energy (3.2 eV in anatase) and its high stability in aqueous solution under UV irradiation."
From the upcoming issue of
Energy and Fuels.
http://pubs.acs.org/cgi-bin/abstract.cgi/enfuem/asap/abs/ef0400619.html